Nitrile Rubber (NBR)

Nitrile Rubber (NBR)

Nitrile rubber, also known as NBR or Buna’ N, is one of the most commonly used sealing elastomers due to its resistance to petroleum-based fuels and lubricants and its relatively low price. Nitrile elastomers are copolymers Of acrylonitrile and butadiene. There are a number of common variations of nitrile compounds.

Acrylonitrile Content

The acrylonitrile (ACN) content of the polymer chains can be varied from 18% to 50%. Lower ACN content gives better bw temperature properties but poorer fuels and polar lubricants. Higher ACN content gives poorer low-temperature properties but improved fuels and polar lubricants resistance. Standard NBRs typically have 34% ACN content.

Cure system – Sulfur-Cured vs. Peroxide-Cured

Standard Nitriles are usually sulfur-cured. Sulfur-cured compounds Offer better low-temperature properties but are more prone to hardening with high temperatures. Peroxide-cured nitriles have better heat resistance and lower expression sets but are more expensive and more difficult to process.

Description

Other Common Variations

  • Nitriles are often internally lubricated to improve ease of installation or reduce friction for dynamic applications.
  • Nitriles can be formulated with only “white list ” ingredients as specified in 21.CFR 177.2600 for use in applications where the elastomer will be in contact with food or beverages.
  • Nitriles can be submitted for approval by the National Sanitation Foundation (NSF) for use in drinking water applications.
  • Nitriles can also be submitted for approval to IJnderwriters Laboratories (UL) for use in applications as prescribed in ULI 57.
  • Nitrile rubber can be combined with polyvinyl Chloride (PVC) to create fuel, ozone and weathering resistance NBR-PVC blends.

Buna is a trademark of ARLANXEO.

Performs Well In…

  • Petroleum-based Oils & fuels
  • Aliphatic hydrocarbons
  • Vegetable oils
  • Silicone Oils & greases
  • Ethylene glycol
  • Dilute acids
    Water to below 100°C (212°F)

Doesn’t Perform Well In…

  • Aromatic hydrocarbons
  • Automotive brake fluid
  • Chlorinated hydrocarbons
  • Ketones
  • Ethers
  • Esters
  • Phosphate ester hydraulic fluids
  • Strong acids
  • Ozone/weathering/sunlight

General Information

ASTM D1418 Designation NBR
ISO/DIN 1629 Designation NBR
ASTM D2000 / SAE J 200 Codes BF, BG, BK, CH
Standard Color(s) Black
Hardness Range 30 to 95 Shore A
Relative Cost Low

Service Temperatures

Standard Low Temperature -40°C -40°F
Standard High Temperature 100°C 212°F
Special Compound Low Temperature -55°C -67°F
Special Compound High Temperature 135°C 275°F